Fritz-Haber-Institut der Max-Planck-Gesellschaft
DFG-Sonderforschungsbereich 555 "Komplexe Nichtlineare
Prozesse"
Fourth International Symposium
Engineering of Chemical Complexity
Berlin, June 7-9, 2006
Program and Organization: G. Ertl, A. S. Mikhailov, H. H. Rotermund
The aim of this meeting is to review current perspectives for design, manipulation and efficient control of self-organizing complex chemical systems, ranging from biotechnology and reactive nanostructures to macroscopic pattern formation in chemical reactors. Both experimental studies of such phenomena and their mathematical modeling will be discussed. Possible technological applications of self-organization phenomena shall be considered.
Invited Speakers
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16:00 – 20:00 Arrival and registration
8:45 Opening: G. Ertl
Session chair: P. De Kepper
9:00
R. Kapral
(Toronto, Canada)
Geometrical effects on spiral defect dynamics
[Abstract]
9:35
Y. Kuramoto
(Sapporo, Japan)
Noise-induced chemical turbulence
[Abstract]
10:10
J. L. Hudson
(Virginia University, USA)
Dynamical order and complexity in populations of electrochemical oscillators
[Abstract]
10:45 – 11:15 Coffee Break
Session chair: R. Kapral
11:15
I. R. Epstein
(Waltham, USA)
Localized structures in reaction-diffusion systems
[Abstract]
11:50
H. Kitahata
(Kyoto, Japan)
Spontaneous motion of a droplet driven by chemical potential or photon flux
Abstract:
Spontaneous motion of a droplet driven by chemical energy gradient or by
electromagnetic energy gradient (photon flux) is realized using simple experimental systems.
Based on the observation of these systems together with recent experimental results reported for
the single molecular experiments on molecular machinery, we will propose a novel hypothesis on
the mechanism of chemo-mechanical energy transduction in living organisms. In our model
experimental systems, we adapted the energy source of chemical energy gradient or by photon
flux to drive the motion of a droplet.
We will report the generation of spontaneous motion on an oil/water system, where the
medium of Belousov-Zhabotinsky reaction is used as an aqueous droplet. It is found that this
spontaneous motion is caused by the convection inside the droplet induced by Marangoni effect
[1]. As the next, we report the occurrence of spontaneous motion of an alcohol droplet on
aqueous phase driven by the solutal Marangoni effect. When alcohol with a relatively long
hydrocarbon chain, such as pentanol, is used, a droplet of alcohol is formed and moves
spontaneously on water for over the period of several hours [2]. Thirdly, vectorial controlled
motion of an oil droplet driven by laser irradiation is described. The direction of a droplet motion
is switched by changing the position where the laser beam is irradiated [3].
The above-mentioned dynamic phenomena on the spontaneous motions of droplets will
contribute not only to help the understanding of the fundamental mechanism on molecular
machinery in biological systems, but also to construct a novel field on nonlinear nonequilibrium
physics.
[1] H. Kitahata, R. Aihara, N. Magome, and K. Yoshikawa, J. Chem. Phys., 116, 5666 (2002).
[2] K. Nagai, Y. Sumino, H. Kitahata, and K. Yoshikawa, Phys. Rev. E., 71, 065301 (2005).
[3] S. Rybalko, N. Magome and K. Yoshikawa, Phys. Rev. E, 70, 046301 (2004).
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12:25 – 14:00 Lunch
Session chair: N. Jaeger
14:00
P. De Kepper
(Bordeaux, France)
The Landolt reaction: Stationary and oscillating fronts in an open spatial reactor with
conical geometry
14:35
A. De Wit
(Brussels, Belgium)
Hydrodynamic instability of autocatalytic reaction fronts
[Abstract]
15:10
O. Steinbock
(Tallahassee, USA)
Three-dimensional wave structures in excitable media
15:45 – 16:15 Coffee break
Session chair: M. Marek
16:15
K. Showalter
(Morgantown, USA)
Collective behavior in addressable excitable media
[Abstract]
16:50
H. Engel
(Berlin, Germany)
Feedback-controlled motion of a spiral wave core along a desired trajectory in an
excitable medium
[Abstract]
Session chair: K. Showalter
9:00
M. Bär
(Berlin, Germany)
Effective models and homogenization in reaction-diffusion processes: from tunable
pattern formation to realistic heart modeling
[Abstract]
9:35
U. Steiner
(Cambridge, UK)
Structure formation in organic-inorganic hybrid materials
10:10
Y. Yokoyama
(Tsukuba, Japan)
Morphology and dynamics of microscopic bubbles in liquid crystals
[Abstract]
10:45 – 11:15 Coffee Break
Session chair: Y. Kevrekidis
11:15
E. Bodenschatz
(Göttingen, Germany)
Spatially forced patterns and hexaroll chaos
[Abstract]
11:50
R. Ismagilov
(Chicago, USA)
Using microfluidics and modular mechanism to understand spatiotemporal dynamics
of complex reaction networks
[Abstract]
12:25 – 14:00 Lunch
Session chair: Y. Nishiura
14:00
Q. Tran-Cong
(Kyoto, Japan)
Reaction-induced hierarchical structures in multiphase polymer materials
14:35
F. Sagués
(Barcelona, Spain)
Langmuir monolayers: textures, flows and dynamic patterns
[Abstract]
15:10
M. Bonn
(Amsterdam, Netherlands)
Site-dependent surface reactivity investigated using nanostructured surfaces
[Abstract]
15:45 – 16:15 Coffee Break
Session chair: J. Hudson
16:15
R. Imbihl
(Hannover, Germany)
Pulses transporting potassium on a Rh(110) surface
16:50
D. Luss
(Houston, USA)
What causes temperature oscillations during CO oxidation in packed bed reactors
17:25
J. Lauterbach
(Newark, USA)
Local microdosing as means to control a nonlinear surface reaction
[Abstract]
19:00 Concert by
Bastian Schäfer
(Berliner Philharmoniker, First Violinist)
Matthew Hunter (Berliner Philharmoniker, Violist)
1. Georg Friedrich Händel, Chaconne in G Major
2. Wolfgang Amadeus Mozart, Duo KV 423, for Violin and Viola
Allegro
Adagio
Rondeau
(the concert takes place in the Ballsaal)
19:30 Dinner
Session chair: E. Bodenschatz
9:00
Y. Nishiura
(Sapporo, Japan)
Entropy and sensitivity of particle patterns in dissipative systems
[Abstract]
9:35
B. Fiedler
(Berlin, Germany)
Kinematics of forced meandering and drifting spirals
10:10
Y. Kevrekidis
(Princeton, USA)
Some examples of coarse-grained computation in complex systems
[Abstract]
10:45 – 11:15 Coffee Break
Session chair: G. Ertl
11:15
M. Marek
(Prague, Czech Republic)
Nonlinear dynamics of forced catalytic mufflers
[Abstract]
11:50
K. Krischer
(München, Germany)
Instabilities and pattern formation during electro-oxidation of H2-CO mixtures in a
fuel cell relevant system
[Abstract]
12:25
M. Falcke
(Berlin, Germany)
By chance or by the clock: How does intracellular calcium oscillate?
13:00
Y. Kuramoto
(Sapporo, Japan)
Early days of the research on coupled oscillators
13:30 Closing
Posters will be presented in the Ballsaal
