DFG-Sonderforschungsbereich 555 "Komplexe Nichtlineare Prozesse"
Fritz-Haber-Institut der Max-Planck-Gesellschaft, Hahn-Meitner-Institut, Otto-von-Guericke-Universität Magdeburg, Physikalisch-Technische Bundesanstalt, Technische Universität Berlin
Seminar
"Complex Nonlinear Processes
in Chemistry and Biology"
Honorary Chairman: Gerhard Ertl
Organizers: | M. Bär, H. Engel, M. Falcke, M. Hauser, A. S. Mikhailov, P. Plath, H. Stark |
Address: | Richard-Willstätter-Haus, Faradayweg 10, 14195 Berlin-Dahlem. (Click here for a description how to get there.) |
For information please contact Oliver Rudzick, Tel. (030) 8413 5300, rudzick@fhi-berlin.mpg.de.
Atsushi Tero
(Hokkaido University, Sapporo, Japan)
Traffic-adaptive networking by a real amoebae of Physarum
[Abstract]
Toshiyuki Nakagaki
(Hokkaido University, Sapporo, Japan)
Amoebae anticipate periodic events
[Abstract]
Takao Ohta
(Department of Physics, Kyoto University, Japan)
Turing patterns in three dimensions
[Abstract]
Karsten Kruse
(Theoretische Physik, Universität des Saarlandes)
Active behavior of the cytoskeleton
[Abstract]
Peter Tass
(Institut für Neurowissenschaften und Biophysik, Forschungszentrum Jülich)
Model based development of desynchronizing brain stimulation techniques
[Abstract]
Pablo Kaluza
(Fritz-Haber-Institut der MPG)
Evolutionary design of complex functional networks
[Abstract]
Hans-Günther Döbereiner
(Institut für Biophysik, Universität Bremen)
Dynamic Phase Transitions and Collective Modes in Cell Spreading
[Abstract]
Hiroya Nakao
(Fritz-Haber-Institut der Max-Planck-Gesellschaft, Berlin)
Phase coherence in an ensemble of uncoupled nonlinear oscillators induced by correlated noise
[Abstract]
Stefan Luther
(Max-Planck-Institut für Dynamik und Selbstorganisation, Göttingen)
Noninvasive adaptive multisite pacing of the heart
[Abstract]
Wolffram Schröer
(Institut für Anorganische und Physikalische Chemie, Universität Bremen)
Criticality and corresponding states in ionic systems
Abstract:
Ionic liquids, which are molten salts with melting points below 100°C,
down to -80°C, are a hot research topic at present.
Many applications in chemical engineering and preparative chemistry are
envisaged for this new fascinating group of compounds.
The interplay of Coulomb interaction and van der Waals interactions
provides a challenge for the theoretical understanding of the special
properties of the ionic liquids and of their solutions. Some ionic liquids
are soluble in non-polar solvents as hydrocarbons others in polar solvents
like water. Vice versa some are insoluble in non-polar others insoluble
in polar solvents.
Liquid-liquid phase transitions are observable at ambient temperatures
enabling investigations of the critical properties (coexistence,
critical fluctuations, critical dynamics) with mK accuracy.
Such research is of fundamental interest: While in nonionic systems
the liquid-gas as well as liquid-liquid phase transitions are driven
by short range van der Waals interactions with an r-6 -range
dependence, the phase transitions in the ionic systems are driven
by long-range r-1 -Coulomb interactions. The universality hypothesis
that liquid-gas as well as liquid-liquid phase transitions all belong
to the Ising universality class has been theoretically proven for
r-n interactions with n>4.97, while the nature of the critical
point in Coulomb systems was unknown.
Some experiments reported mean-field behavior for such systems.
Meanwhile, experiments as well as simulations support the conclusion
that Coulomb systems also belong to the Ising universality class.
The simulations concern the so called restricted primitive model (RPM),
which considers equal sized charged hard spheres in a dielectric continuum.
The critical points of the liquid-liquid phase transitions in ionic solutions
in non-polar solvents are in agreement with the prediction of the RPM.
Corresponding state analysis based on the reduced variables of the
RPM reveals different behavior, when comparing phase separation in
aprotic solvents (hydrocarbons) with that in protic solvents
(alcohols , water). In terms of the RPM- variables the phase
separation in aprotic solvents, which is driven by Coulomb interactions,
have an upper critical solution point, while the coexistence curves
in protic solvents have a lower critical solution point, typically
for phase separation caused by hydrophopic interactions.
Download the seminar program as PDF (ca. 40 kB)
last modified: January 30, 2008 / Oliver Rudzick